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The general mechanism of the addition reaction of aryl esters with vinyl disulfone catalyzed by isothiourea was studied using density functional theory dft and the origin of stereoselectivity and the role of the catalyst were discussed.
An operationally simple approach to e α halo vinyl sulfides and their applications for accessing stereodefined trisubstituted alkenes.
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Teator and leibfarth report a general protocol to polymerize a variety of such vinyl ethers isotactically see the perspective by foster and o reilly.
They rely on a chiral.
The computed results indicate that the reaction can be divided into t.
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Well optimized catalysts produce vast quantities of isotactic polypropylene in which the side chains all face the same way.
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Add an oxygen into the monomer though and that degree of uniformity becomes harder to enforce.
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Organic biomolecular chemistry 2013 11 13 2175.